Try these things one by one until one works:
1. Update your Java
version 1.5 (take the JRE)
2. Delete the LW Preferences folder called
.limewire (whilst LW is closed!) & found here: Windows NT 4.0 / 2000 / XP: C:/Documents And Settings/your_username/.limewire OR Windows 98 / ME: Your .limewire folder is in "C:\My Documents" (BUT make a note of all your LW settings 1st, b/c after you delete the LW prefs folder you'll need to reset them.)
3. Repair LimeWire using the Add/Remove Programs utility. Go to Control Panel then Add/Remove Programs & click on Limewire on the Change/Remove button & it comes up with options and one of them is Repair. Try this.
4. Right-clicking the Limewire icon and going to properties and change compatability setting to Windows 2000.
5. Right-click on the Limewire icon on the desktop and click on Run as. Then it should come up showing the current user and then switch it over to Administrator. (but 'only' if you're the admin of your comp.!)