How do I get my songs off of the Limewire program itself (so I don't need to enqeue or whatever) and put it onto the computer, so I can move around the file, email it, view it in WMP, etc?

For example, I want to get it into a file like this, if you don't really get what I'm talking about:

Just find out where your downloaded files are saved, then you can copy or move them to wherever. If you're going to email them, this folder is where you'll have to look when adding an attachment. Within LW tools > options > saving will show you the location of your saved folder.
If you go to the LW library, click on Saved Files then click Explore...your saved folder will open for you!

I know where the LW folder is, but there isn't any "options" folder..



Is there anything wrong, or am I just in the wrong place?

You're in the wrong place. Just open LW & you'll see tools at the top

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I got it now. thanks!

So I could delete my files off of Limewire now, right?

If you delete files from LW, they're gone. They don't go to the recycle bin.
Just make sure they're safely somewhere else before you delete them